The common measures of stationary phase polarity—McReynolds constants and the polarity scale—are not always accurate predictors of retentiveness or selectivity in GC.
This instalment examines the idea of stationary phase polarity in detail. The assumptions inherent in the most popular stationary phase polarity-evaluating systems—McReynolds constants and the polarity scale—are discussed.
Successful GC analysis requires careful control of carrier gas. Here, we explain how to measure and control flow rate, use constant pressure vs. constant flow, and more.