A simple screening method for Pyrethroid insecticides in sediment samples is described. Electron impact ionization (EI) with tandem MS-MS in combination with programmed temperature vaporization injection (PTV) were used in order to obtain excellent specificity and low limits of detection.
Over the last decade the use of Pharmaceuticals and Personal Care Products (PPCPs) has doubled in the United States. As a result, PPCPs have entered the environment through both human activity and as by-products from manufacturing, agricultural activities, medical use and veterinarian facilities.
Volatile organic compounds (VOCs) in soil were rapidly extracted and concentrated using solid phase microextraction (SPME) followed by on-site analysis and identification with the TRIDION-9 portable gas chromatograph – toroidal ion trap mass spectrometer (GC-TMS). 37 VOCs were resolved and analyzed quickly in under 3 min.
Shale gas reservoirs, such as the Marcellus shale reserve in Pennsylvania and Barnett shale reserve in Texas are a growing source of natural gas in the United States.
Analysis of semi-volatile organic compounds by GC–MS according to well-established methodologies requires integration of a complete system of GC–MS instrumentation and software for data interpretation, analysis, and reporting. While the overall process of analyzing these target compounds is a mature technique, there are continuous innovations that allow laboratories to meet lower detection limits and analyze new compounds to comply with changing regulations, with higher throughput and improved quality.
Air pollution remains a global concern due to its impact on human health and the environment. Compounds known as "air toxics" are of particular importance in this respect, and US EPA methods TO-15 and TO-17 describe how to test air samples for the presence of these compounds.
EPA Method 8270D is used to determine a list of up to 243 semi-volatile organic compounds that are neutral, acidic, basic, and are soluble in methylene chloride. Semi-volatile water samples can contain varying amounts of suspended particulates and/or sediment due to either the source of the water, or the collection technique. By elevating the pH of semi-volatile samples, precipitates can form and result in an emulsion that can create problems for an efficient extraction with traditional techniques. These types of samples, due to their sediment content, have historically proven very challenging when using solid phase extraction (SPE).
The US EPA regulates the testing of 20 specific chlorinated pesticides under the official Method 8081. Zebron MultiResidue columns achieve baseline separation of all of these analytes with short run times, providing greater confidence in identification and increased lab productivity.
Fluoroacetate (Compound 1080) is a strong metabolic poison commonly used as a rodenticide and predacide (1). Due to the high level of toxicity when ingested (2), and no known antidotes, its use has been banned or restricted in many countries.
The update to the SANCO guidelines in 2009 recognized the power and potential of TOF mass spectrometry for pesticide screening applications. When compared with historical screening tools (such as the use of triple-quad mass spectrometry), high performance accurate mass TOF systems offer several advantages for screening applications. These advantages include better resolution, unlimited multiple target capabilities, and the possibility to perform comprehensive and/or retrospective analysis on samples in silico at will.
The use of contrast agents in noninvasive diagnostics provides a specific and high-detailed picture of organs and makes it possible to differentiate between healthy and diseased tissue. Whilst radiocontrast agents (RCA) change the X-ray absorption of the radiographed organ relative to its surrounding tissue, contrast agents for magnetic resonance imaging (MRI) are based on the use of magnetic fields caused by charged elementary particles such as protons and electrons. Compared to traditional X-ray imaging, MRI uses no ionizing radiation. MRI is based on the same principles as NMR spectroscopy and thus takes advantage of the absorption and emission of energy in the radiofrequency range.
The Wisconsin Department of Natural Resources (DNR) Modified Gasoline Range Organics (Wisconsin GRO) Method is used to determine gasoline and gasoline components in water and soil. The optimal hydrocarbon range is from C6-C10 with a boiling point range from 60 ?C–220 ?C (1). The analysis of Wisconsin GRO is vital in determining the "composition and the origin of such products including weathered fuels leaking from underground storage tanks, spills in pipe lines and run-off from surface transportation" (2).
Method 552.1 is a GC method for determination of haloacetic acid and Dalapon in drinking, ground, raw, and other waters at any stage of treatment. This application uses a silica-based quaternary amine anion exchange cartridge, with exceptional recoveries.
This rapid LC–MS method shows sensitive and selective separation of five ethanolamine analytes in wastewater.
Organochlorine pesticides are man-made organic chemicals with a history of wide spread use in the United States, as well as globally.
Aminopolycarboxylate chelating agents form stable complexes with transition metals, thereby increasing metal solubility, preventing metal-catalyzed reactions, and removing heavy metal contamination in soil remediation.
Perfluorinated compounds (PFC) are considered as emerging contaminants that attract high interest from the international scientific community.
Using a bonded polymeric zwitterionic stationary phase, in HILIC mode, polar quaternary herbicides like Diquat can easily be retained, with good peak symmetry.
Pesticide pollution is a subject of global concern, and although many countries have now banned the use of organochlorine pesticides, they linger in the environment and can contaminate water sources.
Using a bonded polymeric zwitterionic stationary phase, in HILIC mode, polar quaternary herbicides like Diquat can easily be retained, with good peak symmetry.
ISOLUTE EPH columns have been developed to fractionate pentane or hexane based soil extracts into aliphatic and aromatic hydrocarbon fractions (C8?C40 aliphatics, C10?C22 aromatics).
In developing the Atomx automated sample prep system, Teledyne Tekmar integrated both a P&T concentrator and a multi-matrix autosampler into a single platform system that can be used in the analysis of soil, water, and soils requiring methanol extraction.
Burning mosquito coils to repel these pests is common in many countries; however the emission of various, potentially toxic volatile organic compounds (VOCs) is cause for concern.
N-Nitrosodimethylamine and other structurally similar nitrosamines are classified as probable carcinogens by the U.S. EPA, and their presence has been reported in California drinking water since 1998.
In this application note we present an online SPE-LC method for the determination of trace-level endocrine disruptive compounds (EDCs) in seawater using the new SolEx HRP cartridge as the solid-phase extraction (SPE) phase.
A sample of ambient cabin air from a commercial airliner was collected by stir bar sorption extraction (SBSE) and analyzed by thermal desorption GCxGC-TOFMS.
Electrochemical detection (ECD) is both selective and extremely sensitive. However, relatively few compounds are electrochemically active, therefore limiting its application.
Gel-permeation chromatography (GPC) is a highly effective postextraction cleanup method for removing high molecular-weight interferences such as lipids, proteins, and pigments from sample extracts prior to analysis.
The fully automated combustion ion chromatography (CIC) system presented here combines a highly efficient combustion system with the separation power of ion chromatography (IC). CIC allows for the simultaneous, speciated trace analysis of halide (F, Cl, Br and I) and sulphur compounds (as sulphate) from sub-ppm to percent levels in any nonaqueous sample matrix.
Bisphenol A (BPA) is widely used in high production volume manufacturing of polycarbonate plastics (for example, food containers and plastic bottles) and epoxy resins.
